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A sensitive multi-residue method for the determination of 35 micropollutants including pharmaceuticals, iodinated contrast media and pesticides in water

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dc.contributor.author Valls Cantenys, Carme
dc.contributor.author Scheurer, Marco
dc.contributor.author Iglesias Juncà, Mònica
dc.contributor.author Sacher, Frank
dc.contributor.author Brauch, Heinz Jürgen
dc.contributor.author Salvadó Martín, Victòria
dc.date.issued 2016-09-01
dc.identifier.issn 1618-2642 (versió paper)
dc.identifier.issn 1618-2650 (versió electrònica)
dc.identifier.uri http://hdl.handle.net/10256/13130
dc.description.abstract A sensitive, multi-residue method using solid-phase extraction followed by liquid chromatography-tandem mass spectrometry (LC-MS/MS) was developed to determine a representative group of 35 analytes, including corrosion inhibitors, pesticides and pharmaceuticals such as analgesic and anti-inflammatory drugs, five iodinated contrast media, β-blockers and some of their metabolites and transformation products in water samples. Few other methods are capable of determining such a broad range of contrast media together with other analytes. We studied the parameters affecting the extraction of the target analytes, including sorbent selection and extraction conditions, their chromatographic separation (mobile phase composition and column) and detection conditions using two ionisation sources: electrospray ionisation (ESI) and atmospheric pressure chemical ionisation (APCI). In order to correct matrix effects, a total of 20 surrogate/internal standards were used. ESI was found to have better sensitivity than APCI. Recoveries ranging from 79 to 134 % for tap water and 66 to 144 % for surface water were obtained. Intra-day precision, calculated as relative standard deviation, was below 34 % for tap water and below 21 % for surface water, groundwater and effluent wastewater. Method quantification limits (MQL) were in the low ng L−1 range, except for the contrast agents iomeprol, amidotrizoic acid and iohexol (22, 25.5 and 17.9 ng L−1, respectively). Finally, the method was applied to the analysis of 56 real water samples as part of the validation procedure. All of the compounds were detected in at least some of the water samples analysed cat
dc.description.sponsorship This study was financed by the SpanishMinistry of Science and Innovation through projects CTM2011-28765-C02-02 and CGL2013-48802-C3-2-R, and an FPI grant (Ref. BES-2009-024892) awarded to C. Valls-Cantenys cat
dc.format.mimetype application/pdf cat
dc.language.iso eng cat
dc.publisher Springer Verlag cat
dc.relation MICINN/PN 2012-2012/CTM2011-28765-C02-02 cat
dc.relation MINECO/PE 2013-2016/CGL2013-48802-C3-2-R cat
dc.relation.isformatof Reproducció digital del document publicat a: http://dx.doi.org/10.1007/s00216-016-9731-5 cat
dc.relation.ispartof © Analytical and Bioanalytical Chemistry, 2016, vol. 408, núm. 22, p. 6189-6200 cat
dc.relation.ispartofseries Articles publicats (D-Q) cat
dc.rights Tots els drets reservats cat
dc.subject Cromatografia de líquids cat
dc.subject Liquid chromatography cat
dc.subject Contaminants emergents en l'aigua cat
dc.subject Emerging contaminants in water cat
dc.subject Aigua -- Contaminació cat
dc.subject Water -- Pollution cat
dc.title A sensitive multi-residue method for the determination of 35 micropollutants including pharmaceuticals, iodinated contrast media and pesticides in water cat
dc.type info:eu-repo/semantics/article cat
dc.rights.accessRights info:eu-repo/semantics/closedAccess cat
dc.embargo.terms Cap cat
dc.type.version info:eu-repo/semantics/publishedVersion cat
dc.identifier.doi http://dx.doi.org/10.1007/s00216-016-9731-5
dc.contributor.funder Ministerio de Ciencia e Innovación (Espanya) cat
dc.contributor.funder Ministerio de Economía y Competitividad (Espanya) cat


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